When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3C(O)_Cameron(2002)_298K_190-248nm.txt |
NAME: | acetyl radical |
FORMULA: | CH3C(O) |
AUTHOR(YEAR): | Cameron(2002) |
T: | 298K |
λ: | 190-248nm |
BIBLIOGRAPHY: |
M. Cameron, V. Sivakumaran, T.J. Dillon, and J.N. Crowley, "Reaction between OH and CH3CHO. Part 1. Primary product yields of CH3 (296 K), CH3CO (296 K), and H (237-296 K)",
Phys. Chem. Chem. Phys. 4, 3628-3638 (2002);
DOI: 10.1039/B202586H
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COMMENTS: | The absorption spectrum was measured using a diode array spectrometer and normalized to the result from the single wavelength experiment, σ(220 nm) = 1.4×10-17 cm2 molecule-1 The listed absorption cross sections were calculated using the fit of the experimental data to the semi-logarithmic Gaussian function (information obtained by personal communication from John Crowley, December 2008) σ(λ) = a1 exp{ -a2 [ln(a3/λ)]2} with a1 = 1.549×10-17 cm2 molecule-1 a2 = 129.19 a3 = 213.985 nm |
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